Re:
Actually it's an interesting question...not straightforward.
Unusually for the Big S they got their straddle-wire philosophy totally wrong in the mid late 90s. I'll explain. The power of cantilevers is governed by some very complex geometry.
1 the precise pull ratio on the lever - which is a complex combination of lever length, arc of pull, etc - how much pull being critical
2 the width of the distance between the brake bosses - which can vary massively on different bikes
3 the height of the brake blocks in the cantilever arms - big adjustment on Onzas, less on S - which determine tyre clearance and the arc of block - and the length of the cantilever arms
4 the height of the straddle wire
5 the length of the straddle wire, affected by how much you put the brake blocks in or out on their posts; how many washers on V brakes, of course.
7 the type of brake cable, with thicker, higher quality stainless cables being best
8 the angle of the wall of the rim, which can vary a lot.
9 the quality of the braking surface, from grippy anodised to glassy coated nastiness
10 brake block surface area and compound
And you have to worry about ankle clearance depending on the position of the bosses.
Now...2-5 and 8 all interact. This affects the ACTUAL LEVERAGE being applied to the rim. It a combination of at least seven different variables regarding setup - with straddle wire angle being one of the most important. There are good articles on this on line. Big S introduced the fixed length half straddle wire (the one with the alloy disc) during the 90's. This fixed the length of the straddle wire. Easy for mechanics in shops, good for safety and their liability. Terrible for setting up brakes, since it removed one of the biggest variables in the brake setup. I had a FS bike at that time and it had LX cantilevers (all pre V brake). They were dreadful. Virtually no stopping power at the rear. Plenty at the front. I ripped them off, put on Critical Racing cantilevers with an old-style straddle with an onZa Chill-pill. Aztec cool-stop brake blocks. Now I could play with all the variables. After an hour of playing (and it had lovely XT levers) i got MASSIVE POWER from the brakes. Cantilevers. MASSIVE POWER. All the right angles in each element of the setup. With a low straddle angle, low straddle length. I kid you not, when V's appeared just after, this cantilever set up was as powerful as Vs. Not more, but about equal to.
So.......the answer to your question.
You could set up either onZa or Shimano so that they are sh+t. Particularly if you use the Shimano half-straddle nonsense.
You can adjust more things on the onZas.
Have a play.
I bet you can get the onZas to be WAYYYY more powerful than the Shimanos.
But then...maybe the boss distance on your bike means that Big S will work better. Who knows? But the above gives you all you need to set the brakes up for maximum power.